Our new paper published in J. Phys. Chem. A uses PHOtoFragment EXcitation (PHOFEX) spectroscopy to pick apart the first absorption band of OCS, the most abundant sulfur-containing molecule in the atmosphere. The PHOFEX spectra obtained probing electronically excited S(1D) and ground state S(3P) atoms are distinctly different; the former is broad and unstructured, while the latter shows distinct resonances that can be attributed to vibrational structure following direct excitation of a quasi-bound triplet state.
The article can be found here: 10.1021/acs.jpca.6b06060